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科研综述张希是清华大学高分子化学与物理领域的学科带头人。他致力于将高分子化学与超分子化学相结合,发展功能超分子体系的分子工程学,取得了一些在中国国内外学术界有影响的成果,主要包括:提出了超两亲分子的新概念,在超分子化学与胶体界面化学之间建立了新的桥梁,并以此实现了可控的分子自组装与解组装,为制备新型功能超分子材料和器件提供了新的途径;建立了基于主体增强非共价作用的超分子聚合新方法,可用于水溶液中组装线型、支化和超支化的超分子聚合物;进而,建立了自分类识别驱动的超分子聚合、超分子单体的共价聚合和超分子界面聚合等几种可控超分子聚合新方法,可用于制备可降解和自修复材料,推动了超分子聚合物领域的发展;提出了超分子自由基的新概念,即以超分子方法稳定或活化的自由基,可用于制备功能超分子材料,并为超分子催化提供新的途径;制备了一系列含硒两亲性嵌段高分子,其具有灵敏的氧化、还原和射线响应等特点,提供了一类新型生物医用材料;建立和发展了基于不同分子间相互作用的界面分子组装方法,并用以制备有机薄膜材料和功能表面;基于单分子力谱技术,研究超分子体系的分子内和分子间相互作用,为从单分子水平认识分子结构、超分子结构及组装驱动力提供了实验依据。学术论著根据2021年7月清华大学网站显示,张希已在中国国内外学术刊物上发表论文350余篇。Zhang, X; Shi, F; Niu, J; et al.Superhydrophobic surfaces: from structural control to functional application. Journal of Materials Chemistry ,2008, 18(6): 621-633Zhang, X; Shi, F; Yu, X; et al.Polyelectrolyte multilayer as matrix for electrochemical deposition of gold clusters: toward super-hydrophobic surface. Journal of the American Chemical Society ,2004, 126(10): 3064-3065Gao, J; Liu, F; Liu, YL; et al.Environment-Friendly Method To Produce Graphene That Employs Vitamin C and Amino Acid. Chemistry of Materials ,2010, 22(7): 2213-2218Zhang, X; Chen, H; Zhang, HYLayer-by-layer assembly: from conventional to unconventional methods. Chemical Communications,2007,(14): 1395-1405Zhang, X; Wang, CSupramolecular amphiphiles. Chemical Society Reviews ,2011, 40(1): 94-101Wang, Yapei; Ma, Ning; Wang, Zhiqiang; et al.Photocontrolled reversible supramolecular assemblies of an azobenzene-containing surfactant with alpha-cyclodextrin. Angewandte Chemie-International Edition ,2007, 46(16): 2823-2826Wang, Chao; Wang, Zhiqiang; Zhang, XiAmphiphilic Building Blocks for Self-Assembly: From Amphiphiles to Supra-amphiphiles. Accounts of Chemical Research ,2012, 45(4): 608-618Wang, LY; Wang, ZQ; Zhang, X; et al.A new approach for the fabrication of an alternating multilayer film of poly(4-vinylpyridine) and poly(acrylic acid) based on hydrogen bonding. Macromolecular Rapid Communications ,1997, 18(6): 509-514Yang, Liulin; Tan, Xinxin; Wang, Zhiqiang; et al.Supramolecular Polymers: Historical Development, Preparation, Characterization, and Functions. Chemical Reviews ,2015, 115(15): 7196-7239Ma, N; Li, Y; Xu, HP; et al.Dual Redox Responsive Assemblies Formed from Diselenide Block Copolymers. Journal of the American Chemical Society ,2010, 132(2): 442-Shi, F; Wang, ZQ; Zhang, XCombining a layer-by-layer assembling technique with electrochemical deposition of gold aggregates to mimic the legs of water striders. Advanced Materials ,2005, 17(8): 1005-Wang, Y; Xu, H; Zhang, XTuning the Amphiphilicity of Building Blocks: Controlled Self-Assembly and Disassembly for Functional Supramolecular Materials. Advanced Materials ,2009, 21(28): 2849-2864Liu, YL; Yu, Y; Gao, JA; et al.Water-Soluble Supramolecular Polymerization Driven by Multiple Host-Stabilized Charge-Transfer Interactions. Angewandte Chemie-International Edition ,2010, 49(37): 6576-6579Zhao, N; Shi, F; Wang, ZQ; et al.Combining layer-by-layer assembly with electrodeposition of silver aggregates for fabricating superhydrophobic surfaces. Langmuir ,2005, 21(10): 4713-4716Yu, X; Wang, ZQ; Jiang, YG; et al.Reversible pH-responsive surface: From superhydrophobicity to superhydrophilicity. Advanced Materials ,2005, 17(10): 1289-Yang, Hui; Yuan, Bin; Zhang, Xi; et al.Supramolecular Chemistry at Interfaces: Host-Guest Interactions for Fabricating Multifunctional Biointerfaces. Accounts of Chemical Research ,2014, 47(7): 2106-2115Liu, Yiliu; Wang, Zhiqiang; Zhang, XiCharacterization of supramolecular polymers. Chemical Society Reviews ,2012, 41(18): 5922-5932Shi, F; Niu, J; Liu, JL; et al.Towards understanding why a superhydrophobic coating is needed by water striders. Advanced Materials ,2007, 19(17): 2257-Sun, JQ; Wu, T; Sun, YP; et al.Fabrication of a covalently attached multilayer via photolysis of layer-by-layer self-assembled films containing diazo-resins. Chemical Communications,1998,(17): 1853-1854学术交流截至2016年,张希在国际性学术会议上做特邀报告和大会报告200多次。2012年6月24-29日,应邀参加在美国弗吉尼亚理工召开的第44届世界高分子大会,并以“单分子力谱与高分子作用”为题做了一小时的大会报告。2016年8月21-25日,应美国化学会邀请中国化学会代表团参加美国化学会第252次年会,并被授予美国化学会会士证书。部分国际学术交流与合作科研成果奖励指导学生截至2017年,张希一共培养博士生50多名,硕士10多名,出站博士后10多名。具体培养学生的信息如下:教育成果奖励1997年,张希获得宝钢教育基金会“优秀教师特等奖”。2005年获得清华大学第八届“良师益友”。